I recently switched to a 7mm-08 for deer. However, I would recommend the .270 Win. You can find ammo for it almost anywhere. The .270 served me well for decades : deer, elk, moose, caribou. I still own two. Carried one for work for many years.
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I've shot deer with a lot of cartridges. Nothing seems to stone them quite as fast as the .308, while still not being overgunned..308 win to be different. No one is doing it these days. Well except for me!
Why would you be looking for something bigger than a 25-06 for deer? I personally would be looking for something smaller that is easier to shoot.